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Scope Details

Reference
Duchesne, A.L., Brown, J.K., Patch, D.J., Major, D., Weber, K.P., and Gerhard, J.I. (2020) Remediation of PFAS-Contaminated Soil and Granular Activated Carbon by Smoldering Combustion - Environmental Science and Technology
Treatment Process
Smoldering
Test Scale
Lab
Matrix
Treatment Media
Matrix Detail
GAC spiked with PFAS
Data Detail
PFOS concentration in matrix before and after treatment; mass in matrix before treatment and in emission collection system at 2 experimental conditions

Condition

Open ConditionTreatment Details
Open Condition 1048250Minute44 g GAC/kg sand; air flux = 5 cm/s; smoldering velocity = 0.45 cm/min; time interpreted from supplemental information Fig S2; temperature represents average peak temperature; exact time sampled after smoldering not given; stated that temperatures at all locations in the treatment zone spent between 10 and 61 min above 900 °C; corresponds to II-1
Open Condition 1011250Minute46 g GAC/kg sand; air flux = 5 cm/s; smoldering velocity = 0.40 cm/min; time interpreted from supplemental information Fig S2; temperature represents average peak temperature; exact time sampled after smoldering not given; stated that temperatures at all locations in the treatment zone spent between 10 and 61 min above 900 °C; corresponds to II-2

Thermal Treatment Results

PFOS1048 °C | 250 minute 182.1 mg/kgNot detectedData from Table S1 in supplemental information; detection limit = 0.0004 mg/kg
PFHxS1011 °C | 250 minute 0.195 mg/kgNot detectedData from Table S1 in supplemental information; detection limit = 0.0004 mg/kg
PFOS1011 °C | 250 minute 197.7 mg/kg0.431 mg/kgData from Table S1 in supplemental information; detection limit = 0.0004 mg/kg
HF1048 °C | 250 minute 45.7% Percent Fluorine Recovery0 mg/kgData from Table 3
HF1011 °C | 250 minute 40.6% Percent Fluorine Recovery0 mg/kgData from Table 3