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Scope Details

Reference
Krause, M. J., Thoma, E., Sahle-Damesessie, E., Crone, B., Whitehill, A., Shields, E., and Gullett, B. (2022) Supercritical Water Oxidation as an Innovative Technology for PFAS Destruction - Journal of Environmental Engineering
Treatment Process
Thermal Oxidation of Off-gas
Test Scale
Lab
Matrix
Treatment Media
Matrix Detail
Aquarden: PFOS-based AFFF material: 3M Lightwater produced prior to 2002. Lightwater produced before 2002 contains both short-chain and long-chain PFAS, including the C8 compounds perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA)
Data Detail
PFAS quantified in the influent or effluent of the SCWO experiments and observed decrease in pH and COD

Condition

Open ConditionTreatment Details
Open Condition 59060SecondPressure (MPa): 24; Oxidizer: Air; Alkaline treatment type: KOH; Alkaline treatment location: Influent

Thermal Treatment Results

PFBA590 °C | 60 second ≈0% Destruction and Removal Efficiency>100 ug/L Aquarden: PFAS quantified in the influent or effluent of the SCWO experiments
PFHpA590 °C | 60 second ≈0% Destruction and Removal Efficiency<1000 ug/L Aquarden: PFAS quantified in the influent or effluent of the SCWO experiments
PFHxA590 °C | 60 second ≈0% Destruction and Removal Efficiency>1000 ug/L Aquarden: PFAS quantified in the influent or effluent of the SCWO experiments
PFOA590 °C | 60 second >0.1% Destruction and Removal Efficiency>0.1 ug/L Aquarden: PFAS quantified in the influent or effluent of the SCWO experiments
PFPeA590 °C | 60 second <1% Destruction and Removal Efficiency<1 ug/L Aquarden:PFAS quantified in the influent or effluent of the SCWO experiments
PFBS590 °C | 60 second <1% Destruction and Removal Efficiency<1 ug/L Aquarden: PFAS quantified in the influent or effluent of the SCWO experiments
PFHxS590 °C | 60 second >1% Destruction and Removal Efficiency>1 ug/L Aquarden: PFAS quantified in the influent or effluent of the SCWO experiments
PFOS590 °C | 60 second >100% Destruction and Removal Efficiency>100 ug/L Aquarden: FAS quantified in the influent or effluent of the SCWO experiments
PFOSA590 °C | 60 second =1% Destruction and Removal Efficiency=1 ug/L Aquarden: PFAS quantified in the influent or effluent of the SCWO experiments