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Scope Details

Reference
Hori, H., Nagaoka, Y., Sano, T., and Kutsuna, S. (2008) Iron-induced decomposition of perfluorohexanesulfonate in sub-and supercritical water - Chemosphere
Treatment Process
Hydrothermal Treatment
Test Scale
Lab
Matrix
Other
Matrix Detail
Water heated to super- and sub-critical points, spiked with PFHS and iron powder
Data Detail
Pre- and post-concentrations of PFHS for 6 samples with 4 iron concentrations and 3 initial concentrations

Condition

Open ConditionTreatment Details
Open Condition 3806HourSupercritical water matrix
Open Condition 3506HourSubcritical water matrix

Thermal Treatment Results

PFHxS350 °C | 6 hour 5.93 umol5.48 umolEntry 1; Iron amount = 0 mmol; Reaction pressure = 21.2 MPa; Results from Table 1; Results for hydrogen and carbon dioxide gas-phase products in Table 2
PFHxS350 °C | 6 hour 5.93 umol2.42 umolEntry 2; Iron amount = 4.81 mmol; Reaction pressure = 21.9 MPa; Results from Table 1; Results for hydrogen and carbon dioxide gas-phase products in Table 2
PFHxS350 °C | 6 hour 5.93 umol0.97 umolEntry 3; Iron amount = 9.61 mmol; Reaction pressure = 22.1 MPa; Results from Table 1; Results for hydrogen and carbon dioxide gas-phase products in Table 2
PFHxS350 °C | 6 hour 5.93 umol0.78 umolEntry 4; Iron amount = 19.3 mmol; Reaction pressure = 23 MPa; Results from Table 1; Results for hydrogen and carbon dioxide gas-phase products in Table 2
PFHxS350 °C | 6 hour 3.01 umol0.46 umolEntry 5; Iron amount = 9.61 mmol; Reaction pressure = 22 MPa; Results from Table 1; Results for hydrogen and carbon dioxide gas-phase products in Table 2
PFHxS350 °C | 6 hour 1.46 umolNDEntry 6; Iron amount = 9.61 mmol; Reaction pressure = 21.9 MPa; Results from Table 1; Results for hydrogen and carbon dioxide gas-phase products in Table 2
F350 °C | 6 hour Not reported2.52 umolEntry 1; Iron amount = 0 mmol; Reaction pressure = 21.2 MPa; Results from Table 1; Results for hydrogen and carbon dioxide gas-phase products in Table 2
F350 °C | 6 hour Not reported21.3 umolEntry 2; Iron amount = 4.81 mmol; Reaction pressure = 21.9 MPa; Results from Table 1; Results for hydrogen and carbon dioxide gas-phase products in Table 2
F350 °C | 6 hour Not reported22.2 umolEntry 3; Iron amount = 9.61 mmol; Reaction pressure = 22.1 MPa; Results from Table 1; Results for hydrogen and carbon dioxide gas-phase products in Table 2
F350 °C | 6 hour Not reported31.1 umolEntry 4; Iron amount = 19.3 mmol; Reaction pressure = 23 MPa; Results from Table 1; Results for hydrogen and carbon dioxide gas-phase products in Table 2
F350 °C | 6 hour Not reported11.8 umolEntry 5; Iron amount = 9.61 mmol; Reaction pressure = 22 MPa; Results from Table 1; Results for hydrogen and carbon dioxide gas-phase products in Table 2
F350 °C | 6 hour Not reported6.27 umolEntry 6; Iron amount = 9.61 mmol; Reaction pressure = 21.9 MPa; Results from Table 1; Results for hydrogen and carbon dioxide gas-phase products in Table 2
CHF3350 °C | 6 hour Not reportedNot reported00.4 umolEntry 1 - same trial as Entry 2 in Table 1; Iron amount = 4.81 mmol; Reaction pressure = 21.9 MPa; Results from Table 2; Results for hydrogen and carbon dioxide gas-phase products in Table 2
CHF3350 °C | 6 hour Not reportedNot reported00.49 umolEntry 2 - same trial as Entry 3 in Table 1; Iron amount = 9.61 mmol; Reaction pressure = 22.1 MPa; Results from Table 2; Results for hydrogen and carbon dioxide gas-phase products in Table 2
CHF3350 °C | 6 hour Not reportedNot reported00.56 umolEntry 3 - same trial as Entry 4 in Table 1; Iron amount = 19.3 mmol; Reaction pressure = 23 MPa; Results from Table 2; Results for hydrogen and carbon dioxide gas-phase products in Table 2
CHF3350 °C | 6 hour Not reportedNot reported00.25 umolEntry 4 - same trial as Entry 3 in Table 1; Iron amount = 9.61 mmol; Reaction pressure = 22 MPa; Results from Table 2; Results for hydrogen and carbon dioxide gas-phase products in Table 2
CHF3350 °C | 6 hour Not reportedNot reported00.13 umolEntry 5 - same trial as Entry 4 in Table 1; Iron amount = 9.61 mmol; Reaction pressure = 21.9 MPa; Results from Table 2; Results for hydrogen and carbon dioxide gas-phase products in Table 2
PFHxS380 °C | 6 hour 5.93 umol4.14 umolEntry 1; Iron amount = 0 mmol; Reaction pressure = 23.8 MPa; Results from Table 3; Results for hydrogen and carbon dioxide gas-phase products in Table 3
PFHxS380 °C | 6 hour 5.93 umol0.31 umolEntry 2; Iron amount = 9.61 mmol; Reaction pressure = 26.4 MPa; Results from Table 3; Results for hydrogen and carbon dioxide gas-phase products in Table 3
F380 °C | 6 hour Not reported7.08 umolEntry 1; Iron amount = 0 mmol; Reaction pressure = 23.8 MPa; Results from Table 3; Results for hydrogen and carbon dioxide gas-phase products in Table 3
F380 °C | 6 hour Not reported36.3 umolEntry 2; Iron amount = 9.61 mmol; Reaction pressure = 26.4 MPa; Results from Table 3; Results for hydrogen and carbon dioxide gas-phase products in Table 3
CHF3380 °C | 6 hour Not reportedNot reportedNot reportedEntry 1; Iron amount = 0 mmol; Reaction pressure = 23.8 MPa; Results from Table 3; Results for hydrogen and carbon dioxide gas-phase products in Table 3
CHF3380 °C | 6 hour Not reportedNot reported3.66 umolEntry 2; Iron amount = 9.61 mmol; Reaction pressure = 26.4 MPa; Results from Table 3; Results for hydrogen and carbon dioxide gas-phase products in Table 3
PFHxS350 °C | 6 hour 5.93 umol0.6 umolEntry 1; Iron type = A, 3 to 5 um; Iron amount = 9.61 mmol; Reaction pressure = 23 MPa; Results from Table 4; Results for hydrogen and carbon dioxide gas-phase products in Table 4
PFHxS350 °C | 6 hour 5.93 umol0.97 umolEntry 2; Iron type = B, <53 um; Iron amount = 9.61 mmol; Reaction pressure = 22.1 MPa; Results from Table 4; Results for hydrogen and carbon dioxide gas-phase products in Table 4
PFHxS350 °C | 6 hour 5.93 umol4.76 umolEntry 3; Iron type = C, <180 um; Iron amount = 9.61 mmol; Reaction pressure = 21.2 MPa; Results from Table 4; Results for hydrogen and carbon dioxide gas-phase products in Table 4
F350 °C | 6 hour Not reported40.3 umolEntry 1; Iron type = A, 3 to 5 um; Iron amount = 9.61 mmol; Reaction pressure = 23 MPa; Results from Table 4; Results for hydrogen and carbon dioxide gas-phase products in Table 4
F350 °C | 6 hour Not reported22.2 umolEntry 2; Iron type = B, <53 um; Iron amount = 9.61 mmol; Reaction pressure = 22.1 MPa; Results from Table 4; Results for hydrogen and carbon dioxide gas-phase products in Table 4
F350 °C | 6 hour Not reported10.4 umolEntry 3; Iron type = C, <180 um; Iron amount = 9.61 mmol; Reaction pressure = 21.2 MPa; Results from Table 4; Results for hydrogen and carbon dioxide gas-phase products in Table 4
CHF3350 °C | 6 hour Not reportedNot reported00.3 umolEntry 1; Iron type = A, 3 to 5 um; Iron amount = 9.61 mmol; Reaction pressure = 23 MPa; Results from Table 4; Results for hydrogen and carbon dioxide gas-phase products in Table 4
CHF3350 °C | 6 hour Not reportedNot reported00.49 umolEntry 2; Iron type = B, <53 um; Iron amount = 9.61 mmol; Reaction pressure = 22.1 MPa; Results from Table 4; Results for hydrogen and carbon dioxide gas-phase products in Table 4
CHF3350 °C | 6 hour Not reportedNDNot reportedEntry 3; Iron type = C, <180 um; Iron amount = 9.61 mmol; Reaction pressure = 21.2 MPa; Results from Table 4; Results for hydrogen and carbon dioxide gas-phase products in Table 4